Surfactant composition

ABSTRACT

A surfactant composition comprising a sugar-based surfactant comprising a C8-C16 alkyl glucoside, a C8-C16 alkyl polyglucoside, or a combination of a C8-C16 alkyl glucoside and a C8-C16 alkyl polyglucoside; a C8-C18 amphodiacetate; a C8-C16 acyl sarcosinate, a C8-C16 acyl glutamate, a C8-C16 acyl glycinate, or a combination thereof; and optionally a C8-C14 acyl lactylate, wherein the composition is free of sulfated anionic surfactants.

CROSS REFERENCE TO RELATED APPLICATION

This application claims the benefit under 35 U.S.C. §119(e) of U.S.provisional patent application Ser. No. 62/352,555, filed Jun. 20, 2016,the entire disclosure of which is incorporated herein by reference, ishereby claimed.

FIELD OF INVENTION

The present disclosure is directed to surfactant compositions, moreparticularly, to sulfate-free surfactant compositions which are capableof producing stable foam. A method of generating a stable foam is alsodisclosed.

BACKGROUND OF INVENTION

Foam is an important property of cleaning compositions, especially forpersonal care compositions, such as hair shampoos, body gels,dentifrices, and shaving creams. Esthetically, foam is an importantproperty because consumers equate a rich, long-lasting foam to a highquality product that works well. Functionally, foam is an importantproperty because the foam first acts as a carrier to deliver cleaningsurfactants to the skin or hair, then acts as a carrier to help removeemulsified soil and sebum from the cleaned skin or hair.

However, to achieve these esthetic and functional goals, the foam mustbe present in a wet, or spherical, form. If the generated foam isunstable, the foam changes from the wet form to the dry, or hexagonal,form relatively quickly, i.e., in less than about two minutes. Dry foambubbles break quickly, and, therefore, for dermatogically preferredcompositions do not provide the esthetic and functional foam propertiestypically required for consumer acceptance of the composition.

Foam is created by dispersing air or a gas in a surfactant-containingliquid. The mechanism of dispersing a gas in a surfactant-containingliquid is similar to the dispersion of two immiscible liquids duringformation of an emulsion. Consequently, gas bubbles dispersed in aliquid are stabilized in the same manner as emulsions, i.e., byformation of surfactant layers at the gas-liquid interface. Thesurfactant layers keep the gas bubbles separated and prevent“coalescence,” i.e., the merging of small gas bubbles to form larger gasbubbles. In general, more dense and more compact surfactant layers formsmaller bubbles and retard the coalescence mechanism.

It is well known that because of the very large density differencebetween the dispersed gas and the liquid, the gas bubbles rise to thetop of the liquid. The enriched concentration of gas bubbles at the topof the liquid appear as “foam.” Initially, all of the gas bubbles in thefoam are spherical, there is sufficient space between each individualspherical gas bubble for the presence of the surfactant-containingliquid, and the foam behaves like an emulsion. Such a foam is termed a“wet foam.”

Over time, the liquid present in the interstices between the individualgas bubbles drains out due to gravity. Depending on the nature andchemical structure of the surfactant in the liquid, lamellar liquidcrystalline layers form and arrange at the gas-liquid interface. If thelamellar layers have a low viscosity, the surfactant-containing liquidbetween individual gas bubbles can drain relatively easily, and thespherical form of the foam bubbles can change into a hexagonal formrelatively quickly. Hexagonal bubbles quickly break. The transition of afoam from the spherical form to the hexagonal form due to foam aging canbe observed visually. Foam in the hexagonal form is termed a “dry foam.”Dry foams are unstable, which leads to a rapid reduction in foam volumedue to rapidly breaking bubbles.

However, if the lamellar surfactant layers have a relatively higherviscosity, the transition from a spherical foam to the hexagonal formcan be delayed. The speed of the transition of a foam from the sphericalto hexagonal form determines how the foam is used in practicalapplications, and also determines how the foam is perceivedesthetically. For example, for shampoos and shower gels, foams having afoam transition of about two minutes or less, i.e., a metastable foamstructure, is desirable. Foam stability is controlled by many factorsassociated with the physiochemical properties of the surfactant solutionsuch as surface tension, film surface tension (lamellar foams), surfaceviscosity and elasticity amongst others. A more stable foam could leadto insufficient wetting and distribution of the surfactant on the skinor hair, because during application of the shampoo or shower gel to theskin or hair, some parts of that foam undergo the transition tohexagonal state that allows the surfactant to drain from between thebubbles to contact and wet the hair or skin. Then, by continual rubbingof the shampoo or shower gel on the skin or hair, new foam bubbles aregenerated, which act as a carrier to lift and remove soil and sebum fromthe skin or hair and additional water rinses it off. Esthetically,spherical foam is desired. Functionally, the transition to the hexagonalform and regeneration of the spherical foam provides cleansing.

Other foam applications, e.g., shaving foams, require a foam having amuch greater stability because the applied foam is not regenerated bycontinual rubbing techniques and because of the relatively long timerequired to complete the entire shaving operation. Furthermore, acontrolled and sufficient wetting of the hair and skin is required for asmooth shaving operation. Sufficient wetting when a surfactant is foamedoccurs only if the surfactant-containing liquid can drain from the foamlamellae to contact the skin, and drainage occurs more readily when thefoam bubbles are in the spherical form.

The difference in structure between a wet, spherical foam and a dry,hexagonal foam is illustrated in FIGS. 3 and 4 of U.S. Pat. No.5,911,811. FIG. 3 of U.S. Pat. No. 5,911,811 clearly shows both thelamellar liquid crystalline surfactant structure that stabilizes eachbubble of a wet foam and the large amount of surfactant-containingliquid between individual bubbles. The relatively thick surfactantstructure illustrated in FIG. 3 also retards the coalescence ofneighboring bubbles into a single, larger bubble. In contrast, FIG. 4 ofU.S. Pat. No. 5,911,811 shows a lack of a stabilizing surfactantstructure around the hexagonal bubbles and the relative absence ofsurfactant-containing liquid between the bubbles.

The most commonly used sulfated anionic surfactants are well known forproviding a high volume of a stable foam and having an excellent abilityto emulsify soils and oils, i.e., to act as an efficient cleaner of skinand hair. Sulfated anionic surfactants include the anionic sulfates andthe anionic sulfonates. As a result of these properties, sulfatedanionic surfactants have been the primary surfactant used in shampoosand other skin and hair cleaning products. However, sulfated anionicsurfactants have disadvantages. For example, the sulfated anionicsurfactants strip the hair of natural oils that condition the hair andthereby can damage the hair and give freshly shampooed hair a dry feel.Sulfated anionic surfactants also are harsh to the skin and eyes, andthus sulfated anionic surfactants are generally unsuitable for use inbaby shampoos and pet products.

Amphoteric and nonionic surfactants are relatively mild to the skin andeyes and do not strip the hair of natural oils. However, amphoteric andnonionic surfactants typically generate a poor foam in comparison to asulfated anionic surfactant. Therefore, shampoos and similar cleanersbased primarily on amphoteric and nonionic surfactants have not achievedgood consumer acceptance. But, amphoteric and nonionic surfactants havebeen used in conjunction with sulfated anionic surfactants in attemptsto provide a shampoo that takes advantage of the foaming properties of asulfated anionic surfactant, while tempering the disadvantageousproperties of the sulfated anionic surfactant with a nonionic oramphoteric surfactant.

DETAILED DESCRIPTION

The disclosure provides sulfate-free surfactant compositions that arecapable of producing a stable foam that remain in the wet, or spherical,form for at least as long as a comparable sulfate-based product.Beneficially, the disclosed surfactant compositions are free of sulfatedanionic surfactants. Further, the disclosed surfactant compositions donot cause adverse reactions and thus are suitable for a number of usesincluding but not limited to applications where a milder surfactantcomposition may be desired such as in baby shampoos and pet products.Thus, the surfactant compositions according to the disclosure are freeof lauryl ether sulfates, lauryl sulfates, and sulfonates. In thecontext of this disclosure, the term “free of sulfated anionicsurfactants” means that a sulfated anionic surfactant is notintentionally added to a surfactant composition according to thedisclosure, but may be present as a by-product or contaminant such thata surfactant composition according to the disclosure may contain 0% toabout 0.1% by weight of a sulfated anionic surfactant.

In one embodiment, the disclosure provides a surfactant compositioncomprising a sugar-based surfactant comprising a C8-C16 alkyl glucoside,a C8-C16 alkyl polyglucoside, or a combination of a C8-C16 alkylglucoside and a C8-C16 alkyl polyglucoside; a C8-C18 amphodiacetate; aC8-C16 acyl sarcosinate, a C8-C16 acyl glutamate, a C8-C16 acylglycinate, or a combination thereof; and optionally a C8-C14 acyllactylate, wherein the composition is free of sulfated anionicsurfactants.

In another embodiment, the disclosure provides a method of generating astable, wet foam comprising adding a surfactant blend according to thedisclosure to an aqueous composition to provide an aqueous mixture, andforming bubbles from the aqueous mixture of step to generate the stable,wet foam.

The sugar-based surfactant comprising at least one of a C8-C16 alkylglucoside and/or a C8-C16 alkyl polyglucoside is typically a non-ionicsugar-based (i.e., glucose-based) surfactant but may also be a salt of asugar-based surfactant. The sugar-based surfactant may be present in thesurfactant compositions according to the disclosure in an amount betweenabout 10 weight percent (wt. %) and about 40 wt. %, between about 15 wt.% and about 35 wt. %, and/or between 20 wt. % and about 30 wt. %. Thesugar-based surfactant can be prepared/derived from the 6-carbonmonosaccharide glucose and C8-C16 alcohols. Suitable C8-C16 alkylglucosides include but are not limited to: decyl glucoside, heptylglucoside, octyl glucoside, lauryl glucoside (or dodecyl glucoside),coco-glucosides (which is a mixture of C8-C16 alkyl glucosides), andcombinations thereof. Suitable C8-C16 alkyl polyglucosides include butare not limited to: disodium coco-glucoside citrate, sodiumcoco-glucoside tartrate, and combinations thereof. Combinations of oneor more C8-C16 alkyl glucosides and one or more C8-C16 alkylpolyglucosides may also be used. In one aspect, the sugar-basedsurfactant is the primary surfactant in the composition, i.e., thesugar-based surfactant is present in an amount greater than any othersurfactant in the composition.

The C8-C18 acyl amphodiacetate typically serves as a secondarysurfactant and a foam booster in the surfactant compositions accordingto the disclosure. The C8-C18 acyl amphodiacetate may be prepared byprocedures including a step in which aminoethylethanolamine is reactedwith fatty acyl compounds. The C8-C18 acyl amphodiacetate is anamphoteric surfactant typically having the following formula (I):

wherein R may be C8-C18 alkyl or C8-C18 alkenyl. While theamphodiacetate of formula (I) includes sodium as the counter ion, otheralkaline metals may also be used. The C8-C18 acyl amphodiacetate may bepresent in the surfactant compositions according to the disclosure in anamount between about 5 weight percent (wt. %) and about 25 wt. %,between about 10 wt. % and about 20 wt. %, and/or between 12 wt. % andabout 18 wt. %. Suitable C8-C18 acyl amphodiacetates include but are notlimited to: capryl amphodiacetate, lauryl amphodiacetate (or dodecylamphodiacetate), cocoamphodiacetate (which is a mixture of C8-C16 acylamphodiacetates), and combinations thereof.

The C8-C16 acyl sarcosinate, C8-C16 acyl glutamate, and/or C8-C16 acylglycinate is an anionic surfactant derived from the amino acidsarcosine, glutamine, or glycine, respectively, and a correspondingC8-C16 fatty acid. The C8-C16 acyl sarcosinate, C8-C16 acyl glutamate,and/or C8-C16 acyl glycinate may be present in the surfactantcompositions according to the disclosure in an amount between about 10weight percent (wt. %) and about 35 wt. %, between about 15 wt. % andabout 30 wt. %, and/or between 20 wt. % and about 25 wt. %. SuitableC8-C16 acyl sarcosinates include but are not limited to: sodium lauroylsarcosinate, sodium cocoyl sarcosinate (which is a mixture of sodiumC8-C16 acyl sarcosinates), sodium myristoyl sarcosinate, ammoniumlauroyl sarcosinate, ammonium cocoyl sarcosinate, isopropyl lauroylsarcosinate, potassium cocoyl sarcosinate, potassium lauroylsarcosinate, and combinations thereof; suitable C8-C16 acyl glutamatesinclude but are not limited to: sodium lauroyl glutamate, sodium cocoylglutamate (which is a mixture of sodium C8-C16 acyl glutamates), sodiummyristoyl glutamate, ammonium lauroyl glutamate, ammonium cocoylglutamate, isopropyl lauroyl glutamate, potassium cocoyl glutamate,potassium lauroyl glutamate, and combinations thereof; suitable C8-C16acyl glycinates include but are not limited to: sodium lauroylglycinate, sodium cocoyl glycinate (which is a mixture of sodium C8-C16acyl glycinates), sodium myristoyl glycinate, ammonium lauroylglycinate, ammonium cocoyl glycinate, isopropyl lauroyl glycinate,potassium cocoyl glycinate, potassium lauroyl glycinate, andcombinations thereof. Combinations of one or more C8-C16 acylsarcosinates, C8-C16 acyl glutamates, and/or C8-C16 acyl glycinates mayalso be used. For example, a combination of one or more C8-C16 acylsarcosinate and one or more C8-C16 acyl glycinate may be used.Similarly, for example, a combination of one or more C8-C16 acylsarcosinate and one or more C8-C16 acyl glutamate may be used.Combinations of one or more C8-C16 acyl sarcosinate, one or more C8-C16acyl glutamate, and one or more C8-C16 acyl glycinate also may be used.

The C8-C14 acyl lactylate is an anionic surfactant that typically servesas a foam booster and viscosity enhancer in the surfactant compositionsaccording to the disclosure. The combination of the C8-C14 acyllactylate with the other components of the surfactant combinations, inparticular with the sugar-based surfactant comprising a C8-C14 alkylglucoside, has been found to be particularly effective for enhancingfoam quality. The C8-C14 acyl lactylate may be present in the surfactantcompositions according to the disclosure in an amount between about 0weight percent (wt. %) and about 10 wt. %, between about 0 wt. % andabout 7.5 wt. %, and/or between 1 wt. % and about 4 wt. %. The C8-C14acyl lactylate can be prepared by reacting a C8-C14 fatty acid withlactic acid. Suitable C8-C14 acyl lactylates include but are not limitedto: sodium caproyl lactylate, sodium lauroyl lactylate, sodium myristoyllactylate, and combinations thereof. Of course, ammonium and potassiumsalts may also be used.

The surfactant compositions according to the disclosure may optionallycontain other foam booster and/or viscosity enhancers including but notlimited to surfactants encompassing betaine and sultaine classes,specifically, C8-C16 betaine surfactants such as capryl betaine, decylbetaine, lauryl betaine, myristyl betaine, and C8-C16 sultainesurfactants such as cocamidopropyl sultaine, capryl sultaine, decylsultaine, lauryl sultaine, myristyl sultaine, coco sultaine,cocamidopropyl hydroxysultaine, capryl hydroxysultaine, decylhydroxysultaine, lauryl hydroxysultaine, myristyl hydroxysultaine, cocohydroxysultaine, and mixtures of the foregoing betaine and sultainesurfactants.

In various embodiments, the surfactant compositions may contain fromabout 15 wt. % to about 55 wt. %, about 25 wt. % to about 45 wt. %,and/or about 30 wt. % to about 40 wt. % of water.

Preservatives and/or biocides may also be included in the surfactantcompositions.

In various preferred embodiments, the surfactant compositions accordingto the disclosure are free of one or more of diethanolamines,monoethanol amines, and/or parabens (parahydroxybenzoates). In aparticularly preferred embodiment, the surfactant compositions accordingto the disclosure are free of diethanolamines, monoethanol amines, andparabens (parahydroxybenzoates).

The surfactant compositions according to the disclosure may be used in anumber of different personal care compositions. In particular, thesurfactant compositions according to the disclosure can be incorporatedinto shaving foams, dentrifices, shampoos, shower gels, soaps (bothliquid and bars; hand washes; body washes), and hair care foams such asmousses and dyes.

As used herein any reference to “one embodiment” or “an embodiment”means that a particular element, feature, structure, or characteristicdescribed in connection with the embodiment is included in at least oneembodiment. The appearances of the phrase “in one embodiment” in variousplaces in the specification are not necessarily all referring to thesame embodiment.

In addition, uses of “a” or “an” are employed to describe elements andcomponents of the embodiments described herein. This is done merely forconvenience and to give a general sense of the description. Thisdescription, and the claims that follow, should be read to include oneor at least one, and the singular also includes the plural unless it isclear that it is meant otherwise.

Although the foregoing text sets forth a detailed description ofnumerous different embodiments, it should be understood that the legalscope of the invention is defined by the words of the claims set forthat the end of this patent. The detailed description is to be construedas exemplary only and does not describe every possible embodiment, asdescribing every possible embodiment would be impractical, if notimpossible. One could implement numerous alternate embodiments, usingeither current technology or technology developed after the filing dateof this patent, which would still fall within the scope of the claims.

Example 1

A surfactant composition according to the disclosure was prepared bycombining lauryl glucoside, sodium lauroyl lactylate, sodium lauroylsarcosinate, disodium cocoamphodiacetate, and water in the amounts shownin Table 1.

TABLE 1 Raw Material amount (wt. %) Lauryl Glucoside 25.00 SodiumLauroyl Lactylate 2.50 Sodium Lauroyl Sarcosinate 22.00 DisodiumCocoamphodiacetate 15.00 Water 35.50

The surfactant compositions were found to have excellent foamingproperties comparable or better than a leading brand sulfate basedshampoo (“sulfated benchmark”) and to cause no irritation.

1. A surfactant composition comprising: a sugar-based surfactantcomprising a C8-C16 alkyl glucoside, a C8-C16 alkyl polyglucoside, or acombination of a C8-C16 alkyl glucoside and a C8-C16 alkylpolyglucoside; a C8-C18 amphodiacetate; a C8-C16 acyl sarcosinate, aC8-C16 acyl glutamate, a C8-C16 acyl glycinate, or a combinationthereof; and, wherein the composition is free of sulfated anionicsurfactants.
 2. The surfactant composition according to claim 1 whereinthe sugar-based surfactant is present in an amount between about 10weight percent (wt. %) and about 40 wt. %.
 3. The surfactant compositionaccording to claim 1, wherein the C8-C16 alkyl glucoside comprises decylglucoside, heptyl glucoside, octyl glucoside, lauryl glucoside,coco-glucoside, or a combination thereof.
 4. The surfactant compositionaccording to claim 1, wherein the C8-C16 alkyl polyglucoside comprisesdisodium coco-glucoside citrate, sodium coco-glucoside tartrate, or acombination thereof.
 5. The surfactant composition according to claim 1,wherein the sugar-based surfactant is the primary surfactant in thecomposition.
 6. The surfactant composition according to claim 1, whereinthe C8-C18 acyl amphodiacetate is an amphoteric surfactant having thefollowing formula (I):

wherein R may be C8-C18 alkyl or C8-C18 alkenyl.
 7. The surfactantcomposition according to claim 1, wherein the C8-C18 acyl amphodiacetateis present in an amount between about 5 weight percent (wt. %) and about25 wt. %.
 8. The surfactant composition according to claim 1, whereinthe C8-C18 acyl amphodiacetate comprises capryl amphodiacetate, laurylamphodiacetate, cocoamphodiacetate, or a combination thereof.
 9. Thesurfactant composition according to claim 1, wherein the C8-C16 acylsarcosinate, C8-C16 acyl glutamate, and/or C8-C16 acyl glycinate ispresent in an amount between about 10 weight percent (wt. %) and about35 wt. %.
 10. The surfactant composition according to claim 1, whereinthe C8-C16 acyl sarcosinate comprises sodium lauroyl sarcosinate, sodiumcocoyl sarcosinate, sodium myristoyl sarcosinate, ammonium lauroylsarcosinate, ammonium cocoyl sarcosinate, isopropyl lauroyl sarcosinate,potassium cocoyl sarcosinate, potassium lauroyl sarcosinate, or acombination thereof.
 11. The surfactant composition according to claim1, wherein the C8-C16 acyl glutamate comprises sodium lauroyl glutamate,sodium cocoyl glutamate, sodium myristoyl glutamate, ammonium lauroylglutamate, ammonium cocoyl glutamate, isopropyl lauroyl glutamate,potassium cocoyl glutamate, potassium lauroyl glutamate, or acombination thereof.
 12. The surfactant composition according to claim1, wherein the C8-C16 acyl glycinate comprises sodium lauroyl glycinate,sodium cocoyl glycinate, sodium myristoyl glycinate, ammonium lauroylglycinate, ammonium cocoyl glycinate, isopropyl lauroyl glycinate,potassium cocoyl glycinate, potassium lauroyl glycinate, or acombination thereof.
 13. The surfactant composition according to claim1, further comprising a C8-C14 acyl lactylate.
 14. The surfactantcomposition according to claim 1, wherein the C8-C14 acyl lactylate ispresent in an amount between about 0 weight percent (wt. %) and about 10wt. %.
 15. The surfactant composition according to claim 14 wherein theC8-C14 acyl lactylate comprises sodium caproyl lactylate, sodium lauroyllactylate, sodium myristoyl lactylate, or a combination thereof.
 16. Thesurfactant composition according to claim 1, wherein the surfactantcompositions comprises from about 15 wt. % to about 55 wt. % of water.17. The surfactant composition according to claim 1, wherein thesurfactant composition is free of one or more of diethanolamines,monoethanol amines, and/or parabens (parahydroxybenzoates).
 18. Thesurfactant composition according to claim 1, wherein the surfactantcomposition is free of each of diethanolamines, monoethanol amines, andparabens (parahydroxybenzoates).
 19. A personal care compositioncomprising the surfactant composition according to claim
 1. 20. Apersonal care composition according to claim 19 wherein the personalcare composition is selected from the group consisting of shaving foams,dentrifices, shampoos, shower gels, soaps, and hair care foams.